Product ID:LI'L BROTHER SAM
MSDS Date:07/01/1998
FSC:7930
NIIN:00F020178
Status Code:A
MSDS Number: CLSKZ

STATE CHEMICAL MANUFACTURING CO.

3100 HAMILTON AVENUE
CLEVELAND, OH 44114-3701
US

Emergency Phone: 216-861-7114

Info Phone: 216-861-7114

Cage: 53798

STATE CHEMICAL MANUFACTURING CO.

CLEVELAND, OH 44114-3701 US

Telephone: 216-861-7114

Cage: 53798

HYDROGEN CHLORIDE

CAS: 7647-01-0

RTECS: MW4025000

OSHA PEL 5 PPM

ACGIH TLV: 5 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

PHOSPHORIC ACID

CAS: 7664-38-2

RTECS: TB6300000

OSHA PEL 1 MG/CUM

ACGIH TLV: 1 MG/M3

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ISOPROPANOL (SKIN)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

OXALIC ACID

CAS: 144-62-7

RTECS: RO2450000

OSHA PEL 1 MG/CUM

ACGIH TLV: 1 MG/M3

TOLUENESULFONIC ACID

CAS: 104-15-4

RTECS: XT6300000

Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES CHEMICAL BURNS. INGESTION:
HARMFUL/FATAL. DO NOT GET IN EYES OR ON SKIN. DO NOT BREATHE VAPOR
OR FUMES. NO CHRONIC EFFECTS EXPECTED.
Explanation of Carcinogenicity:NONE

First Aid:INGESTION: IF CONSCIOUS GIVE LARGE AMOUNTS OF WATER TO DILUTE
THE ACID. DON'T ATTEMPT TO MAKE PERSON VOMIT. INHALATION: REMOVE TO
FRESH AIR. KEEP WARM & AT REST. EYES: FLUSH IMMEDIATELY W/PLENTY OF
CO OL WATER FOR 15 MINS. DON'T WEAR CONTACT LENSES WHEN WORKING
W/PRODUCT. SKIN: IMMEDIATELY FLUSH W/WATER. REMOVE WET CLOTHING AND
FLUSH SKIN WITH WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:NONE
Fire Fighting Procedures:WEAR A PRESSURE DEMAND, SCBA TO AVOID POSSIBLE
EXPOSURE TO HYDROGEN CHLORIDE VAPOR.
Unusual Fire/Explosion Hazard:ACID WILL ATTACK MOST METALS W/THE
EVOLUTION OF HYDROGEN.

Spill Release Procedures:VENTILATE AREA. WEARING GLOVES, WIPE OFF
EXCESS LIQUID W/RAGS/OIL ABSORBENT. DILUTE &/NEUTRALIZE & DISPOSE.

Handling and Storage Precautions:HANDLE SOLUTION W/CARE. STORE AT ROOM
TEMP. KEEP CONTAINERS TIGHTLY CLOSED, WHEN NOT IN USE. DON'T REUSE
EMPTY DRUMS. FOR INDUSTRIAL USE ONLY. READ AND FOLLOW ALL LABEL
DIRECTIONS AND PRECAUTIONS BEFO RE USING THE PRODUCT.
Other Precautions:DANGER POISON CAUSES SEVERE CHEMICAL BURNS.
CORROSIVE, CONTAINS HYDROCHLORIC ACID. DON'T BREATHE VAPOR/FUMES.
DON'T GET IN EYES, SKIN/ON CLOTHING. DON'T MIX W/ANY OTHER
CHEMICAL. KEEP OUT OF REACH OF CHILDREN.

Respiratory Protection:IF IN AREA W/LITTLE VENTILATION WEAR NIOSH
RESPIRATOR W/CARTRIDGE FOR ACID FUMES.
Ventilation:USE IN WELL VENTILATED AREAS.
Protective Gloves:RUBBER
Eye Protection:SPLASHPROOF SAFETY GOGGLES
Other Protective Equipment:FULL FACE SHIELD, EYEWASH STATION, SAFETY
SHOWER, RUBBER APRON/PROTECTIVE CLOTHING.
Work Hygienic Practices:READ & FOLLOW LABEL DIRECTIONS & PRECAUTIONS
BEFORE USING THE PRODUCT. NOT FOR HOUSEHOLD USE/RESALE.
Supplemental Safety and Health
% VOLATILES BY WEIGHT=80, WT/GAL=9.61

Boiling Pt:=107.2C, 225.F
Spec Gravity:1.152
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:A CLEAR, GREEN LIQUID WITH A MINT ODOR

Stability Indicator/Materials to Avoid:YES
METALS & STRONG ALKALI. DO NOT MIX THIS PRODUCT WITH ANY OTHER
CHEMICALS
Stability Condition to Avoid:HIGH TEMPS
Hazardous Decomposition Products:NONE

Waste Disposal Methods:OPEN DUMPING PROHIBITED. DISPOSE OF IAW/FEDERAL,
STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.